Comparisons of Measured Rate Constants with Spectroscopically Determined Electron-Transfer Parameters†
نویسندگان
چکیده
منابع مشابه
Comparisons of measured rate constants with spectroscopically determined electron-transfer parameters.
This work involves comparison of rate constants measured for an intervalence (IV) compound with electron-transfer parameters derived from its optical absorption spectrum. The temperature-dependent rate constants for the radical cation having 3-tert-butyl-2,3-diazabicyclo[2.2.2]oct-2-yl (hydrazine) charge-bearing units attached para to a tetramethylbenzene bridge (1+) were previously measured. I...
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Fast kinetic methods are used to measure reactions that take place in less time than required to mix the reagents manually and to measure the reaction by usual methods, like UV-visible spectrophotometry and fluorescence. The best known of them are rapid-mixing and relaxation methods, which are used for reactions with half-times in the millisecond and microsecond ranges, respectively. The picose...
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ژورنال
عنوان ژورنال: The Journal of Physical Chemistry B
سال: 2007
ISSN: 1520-6106,1520-5207
DOI: 10.1021/jp069032k